局部载荷作用简支板屈曲分析

根据能量原理,引入大挠度Von-Karman方程,求解了应力不连续简支板的屈曲问题,得到了临界载荷和临界应力计算系数.     

一种基于STM32的NAND flash的块分配框架设计

STM32对大容量数据文件存储与管理问题可通过NAND flash来解决。而NAND flash的高效管理需要文件系统参与。NAND flash有特殊的块读写及擦除机制,一般的嵌入式文件系统组织结构并不完全兼容NAND flash。针对NAND flash的特点兼顾STM32的资源承受力要提出新的NAND flash块分配框架,框架通过块分配槽这种数据结构,在不使用块分配表与垃圾表的情况下,实现了NAND flash均衡负载与垃圾块的回收;同时通过节点分配栈与文件节点表的配合来提高STM32对文件的读写速度,空间利用率和系统性能。仿真实验和计算结果表明该块分配框架可有效提高NAND flash块的均衡负载与节省RAM空间。     

VxWorks平台内核态ARINC653分区实时调度算法设计与实现

集成模块化航空电子架构(Integrated Modular Avionic, IMA)已成为主流航空电子系统。ARINC 653作为航空电子设备IMA架构的标准应用接口,成为研究航空电子软件编程方法的入口。最新研究表明,VxWorks能够为航空电子分区管理提供最优化的平台。然而,基于VxWorks的ARINC 653高效分区调度算法依然是研究的“盲区”。由此,设计了VxWorks内核态分层ARINC 653分区实时调度算法,提高了分区调度效率,为VxWorks内核ARINC 653完整性的研究提供非常有价值的参考。实验数据说明,相较于传统用户态分区管理模型,该调度算法使分区释放开销和分区释放抖动两项指标均显著降低。     

Superwetting Patterned Membranes with an Anisotropy/Isotropy Transition: Towards Signal Expression and Liquid Permeation

Superwetting membranes with responsive properties have attracted heightened attention because of their fine‐tunable surface wettability. However, their functional diversity is severely limited by the “black‐or‐white” wettability transition. Herein, we describe a coating strategy to fabricate multifunctional responsive superwetting membranes with SiO₂/octadecylamine patterns. The adjustable patterns in the responsive region are the key factor for functional diversity. Specifically, the coated part of the membrane displayed a superhydrophobicity/superhydrophilicity transition at different pH values, whereas the uncoated part exhibited invariant superhydrophilicity. On the basis of this anisotropy/isotropy transition, the membranes can serve as either responsive permeable membranes or signal‐expression membranes, thus enabling the responsive separation and permeation of liquids with satisfactory separation efficiency (>99.90 %) and flux (ca. 60 L m^?2 h), as well as real‐time liquid signal expression with alterable signals.     

Cross-Module Enoylreduction in the Azalomycin F Polyketide Synthase

The colinearity of canonical modular polyketide synthases, which creates a direct link between multienzyme structure and the chemical structure of the biosynthetic end-product, has become a cornerstone of knowledge-based genome mining. Herein, we report genetic and enzymatic evidence for the remarkable role of an enoylreductase in the polyketide synthase for azalomycin F biosynthesis. This internal enoylreductase domain, previously identified as acting only in the second of two chain extension cycles on an initial iterative module, is shown to also catalyze enoylreduction in trans within the next module. The mechanism for this rare deviation from colinearity appears to involve direct cross-modular interaction of the reductase with the longer acyl chain, rather than back transfer of the substrate into the iterative module, suggesting an additional and surprising plasticity in natural PKS assembly-line catalysis.     

Dysprosiacarboranes as Organometallic Single-Molecule Magnets

The dicarbollide ion, nido-C₂B₉H₁₁²⁻ is isoelectronic with cyclopentadienyl. Herein, we make dysprosiacarboranes, namely [(C₂B₉H₁₁)₂Ln(THF)₂][Na(THF)₅] (Ln=Dy, 1Dy ) and [(THF)₃(μ-H)₃Li]₂[{η⁵-C₆H₄(CH₂)₂C₂B₉H₉}Dy{η²:η⁵-C₆H₄(CH₂)₂C₂B₉H₉}₂Li] 3Dy and show that dicarbollide ligands impose strong magnetic axiality on the central Dy^III ion. The effective energy barrier (U_eff) for the loss of magnetization can be varied by the substitution pattern on the dicarbollide. This finding is demonstrated by comparing complexes of nido-C₂B₉H₁₁²⁻ and nido-[o-xylylene-C₂B₉H₉]²⁻, which show a U_eff of 430(5) K and 804(7) K, respectively. The blocking temperature defined by the open hysteresis temperature of 3Dy reaches 6.8 K. Moreover, the linear complex [Dy(C₂B₉H₁₁)₂]⁻ is predicted to have comparable properties with the linear [Dy(Cp^Me3)₂]⁺ complex. As such, carboranyl ligands and their derivatives may provide a new type of organometallic ligand for high-performance single-molecule magnets.     

Ultrastable Surface-Dominated Pseudocapacitive Potassium Storage Enabled by Edge-Enriched N-Doped Porous Carbon Nanosheets

The development of ultrastable carbon materials for potassium storage poses key limitations caused by the huge volume variation and sluggish kinetics. Nitrogen-enriched porous carbons have recently emerged as promising candidates for this application; however, rational control over nitrogen doping is needed to further suppress the long-term capacity fading. Here we propose a strategy based on pyrolysis–etching of a pyridine-coordinated polymer for deliberate manipulation of edge-nitrogen doping and specific spatial distribution in amorphous high-surface-area carbons; the obtained material shows an edge-nitrogen content of up to 9.34 at %, richer N distribution inside the material, and high surface area of 616 m² g⁻¹ under a cost-effective low-temperature carbonization. The optimized carbon delivers unprecedented K-storage stability over 6000 cycles with negligible capacity decay (252 mA h g⁻¹ after 4 months at 1 A g⁻¹), rarely reported for potassium storage.     

基于偶氮苯衍生物的三阶非线性光开关性能的调控

偶氮苯衍生物因其具有特殊的共轭体系常用作光开关特性的三阶非线性光学（NLO）开关材料,但有部分带有特殊基团的偶氮类分子在一般条件下无法显示其性能.然而,这类分子在被调节之后能展示出优异的光控的NLO开关性能.以无光控的NLO开关性能的5-（N-4-偶氮苯基）氨甲基间苯二甲酸为研究对象,并对其潜在的光控NLO开关性能进行调控.经过调节后的这类分子在光照条件下能顺利地经历可逆的顺反异构化反应,且产生三阶非线性性能的转换.其Z-扫描实验结果显示处于反式构型的材料展示出反饱和吸收和自散焦特性;在光照之后,这类材料转化为顺式构型并展现出饱和吸收和自聚焦行为.三阶NLO性能的转换是由于材料的结构发生转变其内部电子产生重排,使得它们在激光刺激下产生不同的响应机制.     

Transport properties and magnetoresistance in La0.8Te0.2MnO3/ZrO2 composites

The transport properties and magnetoresistance of electron-doped manganate / insulator composites (La_0.8Te_0.2MnO₃)_{1 - x}/(ZrO₂)_x (x=0, 0.3, and 0.5) are investigated. It is found that the metal-insulator transition temperature of this system shifts to a lower value as the ZrO₂ content increases. The introduction of ZrO₂ enhances both the domain scattering and electron relative scattering in the metal transport region. In the adiabatic small polaron hopping transport region, the thermal activation energy seems invariable regardless of the ZrO₂ content. The application of a magnetic field promotes the charge transportation capabilities of the composites, and the magnetoresistance is enhanced with an increase of the ZrO₂ content. This could be attributed to the more remarkable modification effect of magnetic field on ordering degree in the composites than in pure La_0.8Te_0.2MnO₃.